SILAKETALS AS TETHERS IN INTRAMOLECULAR RADICAL CYCLISATIONS

DOI: 10.1016/S0040-4039(00)74830-1

Source and publish data:

Tetrahedron Letters p. 573 - 576 (1991)

Update date:2022-08-02

Topics:

Authors:

Hutchinson, John H.

Daynard, Tim S.

Gillard, John W.

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Article abstract of DOI:10.1016/S0040-4039(00)74830-1

Intramolecular radical cyclisation reactions of substrates possessing a silaketal tether proceed predominantly via an endo mode in moderate to good yield to give 7, 8 or 9 membered ring products.The products, which are protected diols, can then be deprote

Full text of DOI:10.1016/S0040-4039(00)74830-1

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