Tetrahedron p. 2835 - 2842 (1991)
Update date:2022-08-04
Topics:
Groth, Ulrich
Schoellkopf, Ulrich
Tiller, Thomas
D-erythro-Sphingosine 9 is a building block of cerebrosides and glycosphingolipids and was synthesized in 5 steps via an asymmetric aldol addition of the lithiated bislactim ether of cyclo-(L-Val-Gly) 4 to (2E)-hexadecenal (3) in an overall yield of 21percent.
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