New chiral synthetic intermediate for prostaglandins

DOI: 10.1016/S0040-4039(00)61103-6

Source and publish data:

Tetrahedron Letters p. 5973 - 5976 (1992)

Update date:2022-08-04

Topics:

Authors:

Takahashi

Shimayama

Miyazawa

Nakazawa

Yamada Yamada

Takatori

Kajiwara

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Article abstract of DOI:10.1016/S0040-4039(00)61103-6

Preparation of an optically active synthetic intermediate 3 starting from D-mannitol and its conversion to PGF2α (1) by using [3+2] cycloaddition of the nitrile oxide derivative of 3 followed by conjugate addition of the vinylzincate to exocyclic enone 2 are described.

Full text of DOI:10.1016/S0040-4039(00)61103-6

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