Differentiation of Isomeric Coordination Geometries by Metal Valence: A Structural Study of its Origin in z (z=0 and 1+)

DOI: 10.1039/c39910000139

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 139 - 141 (1991)

Update date:2022-07-30

Topics:

Authors:

Pramanik, Amitava

Bag, Nilkamal

Ray, Debashis

Lahiri, Goutam Kumar

Chakravorty, Animesh

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000139

In the title complexes Os^II and Os^III display strong preferences for cis- and trans-S4P2 geometries respectively; structural parameters of the cis-Os^II, trans-Os^II and trans-Os^III isomers have revealed that back-bonding and steric crowding within the Os(PPh3)2 fragment are the primary controlling factors.

Full text of DOI:10.1039/c39910000139

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Os(C₂H₅SCS₂)2(P(C₆H₅)3)2

Cas No:134003-98-8

R&D Labs maybe for 134003-98-8

Zhaodu Fine Chemical Plant

Contact:86-310-8067016

Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Shanghai Hanhong Scientific Co.,Ltd.

website:http://www.chemvia.com

Contact:+86-21-64541543,54280654,13918533501

Address:Jiachuan Road 245
Shanghai FWD Chemicals ltd

website:http://www.fwdchem.com

Contact:86-21-54450828

Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District

Relevant to this article

Structure-activity relationships of neuromedin U. I. Contractile activity of dog neuromedin U-related peptides on isolated chicken crop smooth muscle

Doi:10.1248/cpb.43.1148
(1995)
Systematic Evaluation of 2-Arylazocarboxylates and 2-Arylazocarboxamides as Mitsunobu Reagents

Doi:10.1021/acs.joc.8b00486
(2018)
Synthesis of aromatic diterpenes synthesis of 12-hydroxy-abieta-8,11,13-trien-3,7-dione

Doi:10.1080/00397919108020799
(1991)
Design, synthesis, and structure-activity relationships of spirolactones bearing 2-ureidobenzothiophene as acetyl-CoA carboxylases inhibitors

Doi:10.1016/j.bmcl.2011.08.117
(2011)
Enantioselective dirhodium(II)-catalyzed cyclopropanations with trimethylsilylethyl and trichloroethyl aryldiazoacetates

Doi:10.1016/j.tet.2015.05.045
(2015)
Derivatives of R-aminocarnitine without ammonium moiety as liver carnitine palmitoyltransferase I (L-CPTI) Inhibitors

Doi:10.1002/cmdc.201100289
(2011)

Article Doi