Differentiation of Isomeric Coordination Geometries by Metal Valence: A Structural Study of its Origin in z (z=0 and 1+)

DOI: 10.1039/c39910000139

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Journal of the Chemical Society. Chemical communications p. 139 - 141 (1991)

Update date:2022-07-30

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Authors:

Pramanik, Amitava

Bag, Nilkamal

Ray, Debashis

Lahiri, Goutam Kumar

Chakravorty, Animesh

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Article abstract of DOI:10.1039/c39910000139

In the title complexes Os^II and Os^III display strong preferences for cis- and trans-S4P2 geometries respectively; structural parameters of the cis-Os^II, trans-Os^II and trans-Os^III isomers have revealed that back-bonding and steric crowding within the Os(PPh3)2 fragment are the primary controlling factors.

Full text of DOI:10.1039/c39910000139

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