Formation of Novel Bidentate and Crown Thioether Ligands via Dicobalt Alkyne Complexes

DOI: 10.1039/c39910000349

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 349 - 351 (1991)

Update date:2022-08-05

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Authors:

Gelling, Andrew

Jeffery, John C.

Povey, David C.

Went, Michael J.

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Article abstract of DOI:10.1039/c39910000349

Open chain and cyclic thioalkyne complexes capable of ligating metal-carbonyl moieties are prepared by the reaction of CCH2OH)(CO)6> with mono- and di-thiols in the presence of HBF4 and the structures of Mo(CO)4> and (CO)6> have been established by X-ray crystallography; dppm = bis(diphenylphosphino)methane.

Full text of DOI:10.1039/c39910000349

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