Periselective and Enantioselective Carbonyl-Ene Reaction of Isoprene with Fluoroalkyl Glyoxylate Catalysed by Modified Binaphthol-Titanium Complex: Asymmetric Catalytic Synthesis of Enantiomerically Pure Ipsdienol

DOI: 10.1039/c39950002391

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2391 - 2392 (1995)

Update date:2022-08-05

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Authors:

Terada, Masahiro

Mikami, Koichi

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Article abstract of DOI:10.1039/c39950002391

The asymmetric reaction of trifluoroethyl glyoxylate 3d with isoprene 4 catalysed by the modified binaphthol-titanium complex 2b provides the ene product 5d in high periselectivity (92percent) and complete enantioselectivity, which can be converted to ipsdienol 1, a component of the aggregation pheromone of the bark beetle, genus Ips, in enantiomerically pure form.

Full text of DOI:10.1039/c39950002391

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