Journal of the Chemical Society. Chemical communications p. 2391 - 2392 (1995)
Update date:2022-08-05
Topics:
Terada, Masahiro
Mikami, Koichi
The asymmetric reaction of trifluoroethyl glyoxylate 3d with isoprene 4 catalysed by the modified binaphthol-titanium complex 2b provides the ene product 5d in high periselectivity (92percent) and complete enantioselectivity, which can be converted to ipsdienol 1, a component of the aggregation pheromone of the bark beetle, genus Ips, in enantiomerically pure form.
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(1991)
