Alkylaluminium-Catalyzed Claisen Expansion Reactions. Scope and Stereochemistry

DOI: 10.1021/jo00012a014

Source and publish data:

Journal of Organic Chemistry p. 3841 - 3849 (1991)

Update date:2022-08-04

Topics:

Authors:

Paquette, Leo A.

Friedrich, Dirk

Rogers, Robin D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00012a014

The triisobutylaluminium-catalyzed Claisen rearrangement of a series of bicyclic allyl vinyl ethers was examined in connection with a planned synthesis of the diterpene epoxydictymene.The exocyclic vinyl ethers studied undergo <3,3> sigmatropy via chairli

Full text of DOI:10.1021/jo00012a014

Products guided by the article

Product name:C₂₄H₃₄N₂O₂S

Cas No:134153-18-7

R&D Labs maybe for 134153-18-7

Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
Jiangsu Institute of Ecomones Co., Ltd

website:http://www.jsmone.com

Contact:+86-519-82821700

Address:95 Huanyuan N. Road, Jintan, Jiangsu, China
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan

Relevant to this article

Carbenoid entry into trifluoromethylated molecules: Preparation of functionalized CF₃-containing γ, δ-unsaturated carboxylic esters by rhodium-catalyzed reaction of ethyl 3,3,3-trifluoro-2-diazo-propionate with allylic sulfides and their furthe

Doi:10.1016/S0040-4020(01)96907-8
(1991)
Mixed-metal lanthanide-iron triple-decker complexes with a cyclo-P ₅ building block

Doi:10.1002/anie.201102748
(2011)
Asymmetric Bronsted acid catalyzed carbonyl activation - Organocatalytic domino electrocyclization-halogenation reaction

Doi:10.1039/c1cc15289k
(2011)
Comparison of convenient alternative synthetic approaches to 4-[(3-tert-butyldimethylsilyloxy)phenyl]-4-methoxyspiro[1,2-dioxetane-3, 2′-adamantane]

Doi:10.1055/s-2006-942357
(2006)
Carbonyldiimidazole (CDI) mediated synthesis of N^α- protected amino acid azides: Application to the one-pot preparation of ureidopeptides

Doi:10.2174/092986611797200922
(2011)
Structure–activity relationship and hypoglycemic activity of tricyclic matrines with advantage of treating diabetic nephropathy

Doi:10.1016/j.ejmech.2020.112315
(2020)

Article Doi