Alkylaluminium-Catalyzed Claisen Expansion Reactions. Scope and Stereochemistry

DOI: 10.1021/jo00012a014

Source and publish data:

Journal of Organic Chemistry p. 3841 - 3849 (1991)

Update date:2022-08-04

Topics:

Authors:

Paquette, Leo A.

Friedrich, Dirk

Rogers, Robin D.

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Article abstract of DOI:10.1021/jo00012a014

The triisobutylaluminium-catalyzed Claisen rearrangement of a series of bicyclic allyl vinyl ethers was examined in connection with a planned synthesis of the diterpene epoxydictymene.The exocyclic vinyl ethers studied undergo <3,3> sigmatropy via chairli

Full text of DOI:10.1021/jo00012a014

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