Alkylaluminium-Catalyzed Claisen Expansion Reactions. Scope and Stereochemistry

DOI: 10.1021/jo00012a014

Source and publish data:

Journal of Organic Chemistry p. 3841 - 3849 (1991)

Update date:2022-08-04

Topics:

Authors:

Paquette, Leo A.

Friedrich, Dirk

Rogers, Robin D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00012a014

The triisobutylaluminium-catalyzed Claisen rearrangement of a series of bicyclic allyl vinyl ethers was examined in connection with a planned synthesis of the diterpene epoxydictymene.The exocyclic vinyl ethers studied undergo <3,3> sigmatropy via chairli

Full text of DOI:10.1021/jo00012a014

Products guided by the article

Product name:C₂₄H₃₄N₂O₂S

Cas No:134153-18-7

R&D Labs maybe for 134153-18-7

Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Sinonine Industry Co.,Ltd

Contact:86+21-56421993

Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.

Relevant to this article

Carbenoid entry into trifluoromethylated molecules: Preparation of functionalized CF₃-containing γ, δ-unsaturated carboxylic esters by rhodium-catalyzed reaction of ethyl 3,3,3-trifluoro-2-diazo-propionate with allylic sulfides and their furthe

Doi:10.1016/S0040-4020(01)96907-8
(1991)
Mixed-metal lanthanide-iron triple-decker complexes with a cyclo-P ₅ building block

Doi:10.1002/anie.201102748
(2011)
Asymmetric Bronsted acid catalyzed carbonyl activation - Organocatalytic domino electrocyclization-halogenation reaction

Doi:10.1039/c1cc15289k
(2011)
Comparison of convenient alternative synthetic approaches to 4-[(3-tert-butyldimethylsilyloxy)phenyl]-4-methoxyspiro[1,2-dioxetane-3, 2′-adamantane]

Doi:10.1055/s-2006-942357
(2006)
Carbonyldiimidazole (CDI) mediated synthesis of N^α- protected amino acid azides: Application to the one-pot preparation of ureidopeptides

Doi:10.2174/092986611797200922
(2011)
Structure–activity relationship and hypoglycemic activity of tricyclic matrines with advantage of treating diabetic nephropathy

Doi:10.1016/j.ejmech.2020.112315
(2020)

Article Doi