Carbenoid entry into trifluoromethylated molecules: Preparation of functionalized CF3-containing γ, δ-unsaturated carboxylic esters by rhodium-catalyzed reaction of ethyl 3,3,3-trifluoro-2-diazo-propionate with allylic sulfides and their furthe

DOI: 10.1016/S0040-4020(01)96907-8

Source and publish data:

Tetrahedron p. 1629 - 1648 (1991)

Update date:2022-08-04

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Authors:

Shi, Guoqiang

Xu, Yuanyao

Xu, Ming

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Article abstract of DOI:10.1016/S0040-4020(01)96907-8

The [2,3]-sigmatropic rearrangement of sulfonium ylides derived from rhodium-catalyzed decomposition of ethyl 3,3,3-trifluoro-2-diazopropionate in the presence of allylic sulfides affords a variety of functionalized CF₃-containing γ, δ-unsatura

Full text of DOI:10.1016/S0040-4020(01)96907-8

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