Tetrahedron p. 1677 - 1696 (1991)
Update date:2022-08-04
Topics:
Alexakis
Marek
Mangeney
Normant
Propargylic epoxides easily react with Grignard reagents and catalytic amounts of copper(I) salt to afford α-allenic alcohols. The reaction is highly diastereoselective and its stereochemical outcome (syn or anti isomer) can be fully controlled. The syn d
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