Synthesis of the methyl 3-amino-3-deoxy-α- and β-D-allopyranosides and -allofuranosides

Article abstract of DOI:10.1016/0008-6215(91)80125-7

Methyl 3-amino-3-deoxy-α-D-allopyranoside was synthesized from methyl 2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside in a 5-step sequence involving trifluoromethylsulfonylation, azide displacement, deprotection, and catalytic hydrogenation.On displacem