Ketene-diene [4 + 2] cycloaddition products via cation radical initiated diels-alder reaction or vinylcyclobutanone rearrangement

DOI: 10.1021/ja00059a010

Source and publish data:

Journal of the American Chemical Society p. 2165 - 2177 (1993)

Update date:2022-08-02

Topics:

Authors:

Schmittel, Michael

Von Seggern, Heinke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00059a010

Whereas the thermal reaction of the aryl methyl ketenes 1a and 1b with 2 resulted, as anticipated, in the periselective formation of the vinylcyclobutanones 3-6, the aminium ion salt initiated cycloaddition afforded selectively the Diels-Alder products 10

Full text of DOI:10.1021/ja00059a010

Products guided by the article

Product name:(2R,7R)-2-(4-Methoxy-phenyl)-2,3,4,5,6,7-hexamethyl-cyclohepta-3,5-dienone

Cas No:134420-02-3

R&D Labs maybe for 134420-02-3

DUDLEY CHEM CORP

Contact:86-18641848178

Address:
Office Address: Rm.905 Yinhe Building,No.68 Yuexiu Rd,Hexi district,Tianjin,300201.China.
Factory Address: #65,Antai Road,Yimatu Fluorochemical industrial Park,Fuxin City,Liaoning Province,123129,China.
Shanghai Rich Chemicals Co., Ltd

website:http://www.richchemical.com

Contact:+86-21-20255798

Address:Pudong Shanghai,China
Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
Wuhan Jing Chu Chen Pharmaceutical Chemical Co., Ltd.

Contact:027-88877050

Address:Wuhan
Xiamen Huasing Chemicals Co.Ltd.

Contact:0086-592-6228397

Address:NO.24, Xinglin North 2nd Road,Jimei district

Relevant to this article

Synthesis, characterization and mesophase behavior of new liquid crystalline compounds having chalcone as a central linkage

Doi:10.1080/15421406.2011.570123
(2011)
Mechanism of Charge Transfer in the Molecular DPQ Complex Studied by Time-Resolved Fluorescence Spectroscopy

Doi:10.1021/j100170a011
(1991)
A practical synthesis of α-bromo/iodo/chloroketones from olefins under visible-light irradiation conditions

Doi:10.1016/j.cclet.2020.02.022
(2021)
Synthesis and alkylation of spiro-2-oxazolines containing fused 3,4-dihydropyrazin-2(1H)-ones

Doi:10.3987/COM-11-12299
(2011)
Ultrasound-promoted synthesis of 1,5-diarylpenta-2,4-dien-1-ones catalyzed by activated barium hydroxide

Doi:10.1080/00397910902883686
(2009)
Synthesis of functionalized β-lactams and pyrrolidine-2,5-diones through a metal-free sequential ugi-4CR/cyclization reaction

Doi:10.1021/jo5010422
(2014)

Article Doi