Tetrahedron p. 2861 - 2870 (1991)
Update date:2022-08-04
Topics:
Jones, Gurnos
Ollivierre, Hermione
Fuller
Young
3-Methyltriazolothiazole (2) and 3-phenyltriazolothiazole (3) were regiospecifically lithiated at position 6, triazolothiazole (1) at position 6 and 3 with the former predominating. The lithiated triazolothiazoles (4), (10) and (11) reacted with a number of electrophiles to give x:6-disubstituted triazolothiazoles, which could be converted into 2,4-disubstituted thiazoles.
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