SPANamine derivatives in the catalytic asymmetric α-fluorination of β-keto esters

DOI: 10.1016/j.tetasy.2011.08.023

Source and publish data:

Tetrahedron Asymmetry p. 1490 - 1498 (2011)

Update date:2022-08-05

Topics:

Authors:

Jacquet, Olivier

Clement, Nicolas D.

Freixa, Zoraida

Ruiz, Aurora

Claver, Carmen

Van Leeuwen, Piet W.N.M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/j.tetasy.2011.08.023

The use of C₂-symmetric enantiopure nitrogen ligands in the asymmetric catalytic α-fluorination of β-ketoesters is described. SPANamine 1 in the presence of nickel salts gives up to 63% ee in the fluorination of tert-butyl 2-oxocyclopentanecarb

Full text of DOI:10.1016/j.tetasy.2011.08.023

Products guided by the article

Product name:C₄₁H₄₆N₂O₆

Cas No:1346657-32-6

R&D Labs maybe for 1346657-32-6

Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
Beijing Top Science biological technology co., LTD

Contact:+86-13439059536

Address:15-1705 jre three mile, Beijing 100000,CHINA
SICHUAN TONGSHENG AMINOACID CO.LTD

website:http://www.aminoacid.cc

Contact:86-838-2274206/2850606

Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China

Relevant to this article

A multifunctional Pasteurella multocida sialyltransferase: A powerful tool for the synthesis of sialoside libraries

Doi:10.1021/ja0561690
(2005)
Chemical oxidation studies of β-hydroxysulfides with tris(4-bromophenyl)aminium hexachloroantimonate: Diastereoselective sulfoxide obtaining and pinacol-type rearrangement

Doi:10.1081/SCC-120018767
(2003)
NOVEL OXIDATIVE REARRANGEMENT OF β,γ-UNSATURATED KETONE HYDRAZONES ON IODINATION IN BASE

Doi:10.1016/S0040-4039(00)88677-3
(1982)
DINITROGEN VERSUS η⁶-ARENE COORDINATION IN METHYLDIPHENYLPHOSPHINE COMPLEXES OF MOLYBDENUM(0)

Doi:10.1016/S0022-328X(00)87042-4
(1982)
Synthesis of 2,5-Disubstituted 1,3,4-Thiadiazoles from 3-Amino-2-phenyl-4-thioxo-3,4-dihydroquinazoline and Aromatic Aldehydes

Doi:10.1055/s-1982-30009
(1982)
<2 + 2> Cycloaddition of Dichloroketene to Allyl Ethers and Thioethers

Doi:10.1021/jo00392a039
(1987)

Article Doi