Stereocontrolled palladium(0) catalysed cyclisation and cyclisation/carbonylation of pseudoglycal derivatives

DOI: 10.1016/S0040-4020(97)00012-4

Source and publish data:

Tetrahedron p. 3957 - 3974 (1997)

Update date:2022-08-06

Topics:

Authors:

Holzapfel, Cedric W.

Engelbrecht, Gerhard J.

Marais, Lizel

Toerien, Francois

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Article abstract of DOI:10.1016/S0040-4020(97)00012-4

Pd(0) catalysed cyclisations of selected pseudoglycal 1,6-diene and 1,6-enyne derivatives provided annulated pyranoside products in a highly stereospecific fashion. Carbon monoxide insertion reactions of the cyclised σ-Pd intermediates afforded bicyclic c

Full text of DOI:10.1016/S0040-4020(97)00012-4

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