Photochemical Method for Generation of Linear Polyynes: Cycloreversion of Propellatrienes Extruding Indan

DOI: 10.1021/jo00085a003

Source and publish data:

Journal of Organic Chemistry p. 1236 - 1237 (1994)

Update date:2022-08-02

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Authors:

Tobe, Yoshito

Fujii, Toshihiko

Naemura, Koichiro

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Article abstract of DOI:10.1021/jo00085a003

Photolysis of trienediynes 1a and 1b and trienetetrayne 1c having a <4.3.2>propellane framework yielded the respective linear polyynes 2a-c in good efficiency through <2 + 2> cycloreversion, extruding indan (3).

Full text of DOI:10.1021/jo00085a003

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