Butatriene Formation via CuBr-induced Self Coupling of an α-Bromo Vinyl Zinc Reagent: Synthesis and X-Ray Structure of Z-1,1,1,6,6,6-Hexafluoro-2,5-diphenylhexa-2,3,4-triene

DOI: 10.1039/c39910000566

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 566 - 567 (1991)

Update date:2022-08-04

Topics:

Authors:

Morken, Peter A.

Baenziger, Norman C.

Burton, Donald J.

Bachand, Patrick C.

Davis, Charles R.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000566

Title cumulenes 2a and 2b were prepared by reaction of CF3(Ph)C=C(Br)ZnX 1 with CuBr, or by oxidative coupling of 1 with FeCl3 to form 2a,b and 2 3, which can be dehalogenated with zinc to afford 2a,b; the cumulene isomers are readily separated by silica-gel chromatography, and may be prepared in good yield on a multi-gram scale.

Full text of DOI:10.1039/c39910000566

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₁₈H₁₀Br₂F₆

Cas No:134864-39-4

R&D Labs maybe for 134864-39-4

Suzhou Chenke Biotech Co., Ltd.

Contact:+86-18662408853

Address:NO.150, Renai Road, Suzhou Industrial Park
Shenzhen HwaGen Pharmaceutical Co., Ltd

website:http://www.rafflespt.com

Contact:+86-752-5538396

Address:Guangdong Huizhou China
ShangHai BMG Chemical Co., Ltd

Contact:+86-13524845543

Address:Room 602, no 291 sikai road shanghai
Jinan Great Chemical Co.,Ltd.

Contact:+86-531-58668191 58668193 58668196 58661173

Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Shandong Xingshun New Material Co., Ltd.

website:http://www.sd-xingshun.com

Contact:+86-519-86461196

Address:Middle of Luhua East Road, Dingtao District

Relevant to this article

A short and convergent synthesis of the phytoalexins vignafuran, 6-demethylvignafuran, and moracin M via directed lithiation reaction

Doi:10.1248/cpb.39.579
(1991)
Carbon-functionalized 1,4 7-Trithiacyclononanes: Synthesis, Molecular Mechanics and Co-ordination Chemistry

Doi:10.1039/DT9940003165
(1994)
An ESR and HPLC-EC assay for the detection of alkyl radicals

Doi:10.1021/tx015507h
(2001)
Design, synthesis, and spectral parameters of transition metal coordination compounds based on organic autocomplexes

Doi:10.1134/S1070428011100113
(2011)
Synthesis and structure-activity relationship of p-carborane-based non-secosteroidal vitamin D analogs

Doi:10.1016/j.bmc.2014.01.015
(2014)
A simple and efficient asymmetric synthesis of 3-alkyl-isoindolin-1-ones

Doi:10.1016/S0040-4020(02)00462-3
(2002)

Article Doi