Butatriene Formation via CuBr-induced Self Coupling of an α-Bromo Vinyl Zinc Reagent: Synthesis and X-Ray Structure of Z-1,1,1,6,6,6-Hexafluoro-2,5-diphenylhexa-2,3,4-triene

DOI: 10.1039/c39910000566

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 566 - 567 (1991)

Update date:2022-08-04

Topics:

Authors:

Morken, Peter A.

Baenziger, Norman C.

Burton, Donald J.

Bachand, Patrick C.

Davis, Charles R.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000566

Title cumulenes 2a and 2b were prepared by reaction of CF3(Ph)C=C(Br)ZnX 1 with CuBr, or by oxidative coupling of 1 with FeCl3 to form 2a,b and 2 3, which can be dehalogenated with zinc to afford 2a,b; the cumulene isomers are readily separated by silica-gel chromatography, and may be prepared in good yield on a multi-gram scale.

Full text of DOI:10.1039/c39910000566

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₁₈H₁₀Br₂F₆

Cas No:134864-39-4

R&D Labs maybe for 134864-39-4

Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
waho int'l company

Contact:+86-579-85206992

Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai

Relevant to this article

A short and convergent synthesis of the phytoalexins vignafuran, 6-demethylvignafuran, and moracin M via directed lithiation reaction

Doi:10.1248/cpb.39.579
(1991)
Carbon-functionalized 1,4 7-Trithiacyclononanes: Synthesis, Molecular Mechanics and Co-ordination Chemistry

Doi:10.1039/DT9940003165
(1994)
An ESR and HPLC-EC assay for the detection of alkyl radicals

Doi:10.1021/tx015507h
(2001)
Design, synthesis, and spectral parameters of transition metal coordination compounds based on organic autocomplexes

Doi:10.1134/S1070428011100113
(2011)
Synthesis and structure-activity relationship of p-carborane-based non-secosteroidal vitamin D analogs

Doi:10.1016/j.bmc.2014.01.015
(2014)
A simple and efficient asymmetric synthesis of 3-alkyl-isoindolin-1-ones

Doi:10.1016/S0040-4020(02)00462-3
(2002)

Article Doi