GPx-like activity of selenides and selenoxides: Experimental evidence for the involvement of hydroxy perhydroxy selenane as the active species

DOI: 10.1021/ja209570y

Source and publish data:

Journal of the American Chemical Society p. 138 - 141 (2012)

Update date:2022-08-03

Topics:

Authors:

Nascimento, Vanessa

Alberto, Eduardo E.

Tondo, Daniel W.

Dambrowski, Daniel

Detty, Michael R.

Nome, Faruk

Braga, Antonio L.

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Article abstract of DOI:10.1021/ja209570y

The reaction mechanism of the GPx-like oxidation of PhSH with H ₂O₂ catalyzed by selenoxides proceeds via formation of the hydroxy perhydroxy selenane, which is a stronger oxidizing agent than selenoxide. A hydroxy perhydroxy selenan

Full text of DOI:10.1021/ja209570y

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