Radical Translocation Reactions of o-Iodoanilides: The Use of Carbon-Hydrogen Bonds as Precursors of Radicals Adjacent to Carbonyl Groups

DOI: 10.1021/jo00014a001

Source and publish data:

Journal of Organic Chemistry p. 4335 - 4337 (1991)

Update date:2022-08-05

Topics:

Authors:

Curran, Dennis P.

Abraham, Ann C.

Liu, Hongtao

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Article abstract of DOI:10.1021/jo00014a001

The treatment of o-iodoanilides with tributyltin hydride results in radical generation followed by rapid translocation to produce radicals adjacent to carbonyls.These radicals participate in cyclization and asymmetric addition reactions.

Full text of DOI:10.1021/jo00014a001

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