Radical Translocation Reactions of o-Iodoanilides: The Use of Carbon-Hydrogen Bonds as Precursors of Radicals Adjacent to Carbonyl Groups

DOI: 10.1021/jo00014a001

Source and publish data:

Journal of Organic Chemistry p. 4335 - 4337 (1991)

Update date:2022-08-05

Topics:

Authors:

Curran, Dennis P.

Abraham, Ann C.

Liu, Hongtao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00014a001

The treatment of o-iodoanilides with tributyltin hydride results in radical generation followed by rapid translocation to produce radicals adjacent to carbonyls.These radicals participate in cyclization and asymmetric addition reactions.

Full text of DOI:10.1021/jo00014a001

Products guided by the article

Product name:Hept-6-ynoic acid (2-iodo-phenyl)-methyl-amide

Cas No:135190-67-9

R&D Labs maybe for 135190-67-9

Jiande City Silibase Silicone New Material Manufacture Co., Ltd.

Contact:15967177856

Address:Genglou Industrial Development Area
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China

Relevant to this article

Exaltone (=Cyclopentadecanone) from Isomuscone (=Cyclohexadecanone), a one-C-atom ring-contraction methodology via a stereospecific favorskii rearrangement: Regioselective application to (-)-(R)-muscone

Doi:10.1002/hlca.201100398
(2012)
Ansa-ferrocene-incorporated calixpyrroles and calixphyrins: Syntheses and spectral/structural characterization

Doi:10.1021/om300004m
(2012)
Chelating behavior and biocidal efficiency of tryptophan based mixed-ligand complexes

Doi:10.1016/j.inoche.2012.03.016
(2012)
Well-defined PEPPSI-themed palladium–NHC complexes: synthesis, and catalytic application in the direct arylation of heteroarenes

Doi:10.1002/aoc.5387
(2020)
A facile synthesis of 2h-chromenes and 9-functionalized phenanthrenes through reactions between α,β-unsaturated compounds and arynes

Doi:10.1002/ejoc.201200042
(2012)
Coordination chemistry of new chiral P,N ferrocenyl ligands with half-sandwich ruthenium(II), rhodium(III), and iridium(III) complexes

Doi:10.1021/om300738q
(2012)

Article Doi