Cationic but-2-yne complexes of tungsten(II). Preparation and spectral properties of 2-MeC2Me)> (L = neutral monodentate oxygen and sulphur donor ligands). Crystal structure of 2-MeC2Me)>

DOI: 10.1016/0022-328X(89)87100-1

Source and publish data:

Journal of Organometallic Chemistry p. 263 - 272 (1989)

Update date:2022-09-26

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Authors:

Baker, Paul K.

Flower, Kevin R.

Bates, Paul A.

Hursthouse, Michael B.

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Article abstract of DOI:10.1016/0022-328X(89)87100-1

Equimolar quantities of the cationic mono-but-2-yne complex 2-MeC2Me)> and L (L = SC(NH2)2, SC(NMe2)2, SC(NH2)(NHPh-o-Me), SC(NHPh)2, SC(NH2)Me, OC(NH2)2 and OC(NH2)Me) react in acetone at room temperature to give the

Full text of DOI:10.1016/0022-328X(89)87100-1

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Product name:{WI(carbonyl)(acetonitrile)(dppm)(eta.2-but-2-yne)}{tetrafluoroborate}

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