Enantioselective deprotonation of 8-oxabicyclo[3.2.1]octan-3-one systems using homochiral lithium amide bases

DOI: 10.1016/S0040-4020(01)80520-2

Source and publish data:

Tetrahedron p. 207 - 218 (1993)

Update date:2022-08-05

Topics: Enantioselectivity Deprotonation Isolation and Characterization

Authors:

Bunn Bunn

Cox Cox

Simpkins

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80520-2

The asymmetric transformation of oxabicyclic ketones 6 and 7 into non-racemic enol silanes 12 (88% ee) and 10 (85% ee), respectively, was achieved using the homochiral lithium amide base 4. Conversion of 10 into a known key intermediate 15 for C-nucleosid

Full text of DOI:10.1016/S0040-4020(01)80520-2

Products guided by the article

Product name:3,5-Dinitro-benzoic acid (1R,2R,6S,7R,8S)-4,4-dimethyl-9-oxo-3,5,11-trioxa-tricyclo[5.3.1.0^2,6]undec-8-yl ester

Cas No:135273-52-8

R&D Labs maybe for 135273-52-8

Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
HUNAN OUYA BIOLOGICAL CO.,LTD

Contact:+8613400661290

Address:No 908,Kangwan Rd, Liuyang Economic
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District

Relevant to this article

Evaluation of 4,5-Disubstituted-2-Aminoimidazole-Triazole Conjugates for Antibiofilm/Antibiotic Resensitization Activity Against MRSA and Acinetobacter baumannii

Doi:10.1002/cmdc.201100316
(2011)
Synthesis and Pharmacological Evaluation of 1-Phenyl-3-Thiophenylurea Derivatives as Cannabinoid Type-1 Receptor Allosteric Modulators

Doi:10.1021/acs.jmedchem.9b01161
(2019)
Studies on the biodegradation of fosfomycin: Synthesis of ¹³C-labeled intermediates, feeding experiments with rhizobium huakuii PMY1, and Isolation of Labeled Amino Acids from Cell Mass by HPLC

Doi:10.1002/chem.201100725
(2011)
A highly efficient transacetalization of 2-formylpyrrole acetals in alkaline media

Doi:10.1016/j.cclet.2011.10.004
(2012)
The hydrophobically-tagged MDM2-p53 interaction inhibitor Nutlin-3a-HT is more potent against tumor cells than Nutlin-3a

Doi:10.1039/c9cc07795b
(2019)
An expeditious synthesis of iminosugars

Doi:10.1071/CH10211
(2010)

Article Doi