Regiocontrol synthesis of β-trimetylsilyloxy carbonyl compounds through an aldolgrignard elaboration sequence

DOI: 10.1016/S0040-4039(00)74372-3

Source and publish data:

Tetrahedron Letters p. 2525 - 2528 (1991)

Update date:2022-07-30

Topics:

Authors:

Palomo, Caludio

Aizpurua, Jesus M.

Aurrejoetxea, Natalia

Lopez, M. Conception

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)74372-3

Reaction of carbonyl compounds with α-lithio- or α-halozinc N-methoxy-N-methylamides, followed by silylation and Grignard addition resulted in a regiocontrolled synthesis of β-trimethylsilyloxy carbonyl compounds.

Full text of DOI:10.1016/S0040-4039(00)74372-3

Products guided by the article

Product name:7-Phenyl-6-trimethylsilanyloxy-oct-1-en-4-one

Cas No:135388-58-8

R&D Labs maybe for 135388-58-8

Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Jiaozuo Zhongwei Special Products Pharmaceutical Co.,Ltd.

website:http://www.zw-pvp.com

Contact:15302105619

Address:Jiaozuo,Henan,China (Mainland)
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.

Contact:--

Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China

Relevant to this article

Chelate cooperativity and spacer length effects on the assembly thermodynamics and kinetics of divalent pseudorotaxanes

Doi:10.1021/ja2107096
(2012)
Unexpected catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides that form 5-arylaminofuran-2(3 H)-one-4-carboxylates

Doi:10.1021/ol203331r
(2012)
Die Carbonylchrom-, Carbonylmolybdaen- und Carbonylwolfram-Komplexe der Unsymmetrisch Substituierten Phosphinoschwefeldiimide ^tBu2P(NSN)PPh2 und ^tBu2P(NSN)P(^tBu)Ph. 1H, 13C und 31P NMR-Spektroskopische Charakterisierung

Doi:10.1016/0022-328X(91)80005-5
(1991)
Oxime Esters as Novel Irreversible Acyl Transfer Agents for Lipase Catalysis in Organic Media

Doi:10.1039/c39890001533
(1989)
Synthesis and in vitro evaluation of 2-[¹¹C]methoxyestradiol-3, 17β-O,O-bissulfamate for in vivo studies of angiogenesis

Doi:10.1002/jlcr.1930
(2011)
Synthesis of hydroxyl-containing oxindoles and 3,4-dihydroquinolin-2-ones through oxone-mediated cascade arylhydroxylation of activated alkenes

Doi:10.1039/d0gc02205e
(2020)

Article Doi