Cobalt-catalyzed Preparation of Diiminofuran Derivatives through Double Insertion of Isocyanide into a Metal-Carbon Bond

DOI: 10.1246/cl.1991.921

Source and publish data:

Chemistry Letters p. 921 - 924 (1991)

Update date:2022-08-03

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Authors:

Sugano, Kazuyoshi

Tanase, Tomoaki

Kobayashi, Kimiko

Yamamoto, Yasuhiro

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Article abstract of DOI:10.1246/cl.1991.921

The reaction of 2-bromoacetophenone with XylNC (Xyl = 2,6-xylyl) in the presence of Et3N and cobalt complex such as Co2(XylNC)8, CoBr2(XylNC)4, (PF6) or Co(acac)3, gave 2,3-bis-N-(2',6'-xylyl)imino-5-phenyl-2,3-dihydrofuran.The structure was c

Full text of DOI:10.1246/cl.1991.921

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