Asymmetric synthesis and biosynthetic implications of (+)-fusarisetin A

DOI: 10.1002/anie.201202455

Source and publish data:

Angewandte Chemie - International Edition p. 7786 - 7789 (2012)

Update date:2022-08-05

Topics:

Authors:

Yin, Jun

Wang, Cheng

Kong, Lili

Cai, Shujun

Gao, Shuanhu

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Article abstract of DOI:10.1002/anie.201202455

Starting from equisetin, the asymmetric synthesis of (+)-fusarisetin A has been accomplished in a one-pot transformation including a biomimetic oxidation and an intramolecular Diels-Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin. Copyright

Full text of DOI:10.1002/anie.201202455

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Product name:fusarisetin A

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