Metal-free aromatic hydrogenation: Aniline to cyclohexyl-amine derivatives

DOI: 10.1021/ja300228a

Source and publish data:

Journal of the American Chemical Society p. 4088 - 4091 (2012)

Update date:2022-07-30

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Authors:

Mahdi, Tayseer

Heiden, Zachariah M.

Grimme, Stefan

Stephan, Douglas W.

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Article abstract of DOI:10.1021/ja300228a

Hydrogenation of the N-bound phenyl rings of amines, imines, and aziridine is achieved in the presence of H₂ and B(C₆F ₅)₃, affording the corresponding N-cyclohexylammonium hydridoborate salts.

Full text of DOI:10.1021/ja300228a

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