Highly Stereoselective SE' Additions of α-Alkoxy Allylstannanes to Chiral Aldehydes. Synthesis of a C-1-C-9 Subunit of Tylonolide

DOI: 10.1021/jo00019a003

Source and publish data:

Journal of Organic Chemistry p. 5493 - 5495 (1991)

Update date:2022-09-26

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Authors:

Marshall, James A.

Yashunsky, Dmitry V.

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Article abstract of DOI:10.1021/jo00019a003

The racemic α-alkoxy allylic stannane RS4 adds to the 2S aldehyde 24 to afford the homoaldol adduct 25 (45percent) derived exclusively from the S enantiomer S4 along with isomerized (R)-γ-alkoxy allylstannane 26 of >80percentee (50percent) and unreacted a

Full text of DOI:10.1021/jo00019a003

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