Synthesis of trifluoromethylalkenes and alkynes. Trifluoromethyl captodative olefins

DOI: 10.1016/0040-4039(91)80692-Y

Source and publish data:

Tetrahedron Letters p. 3071 - 3074 (1991)

Update date:2022-08-05

Topics:

Authors:

Laurent Laurent

Le Drean

Selmi Selmi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80692-Y

β-ethylthio-β-trifluoromethylketones 3 and aldehydes 4 are easily prepared from β-chloroolefines 5 and 6. Trifluoromethylalkynes 7 and captodative alkenes 8 are obtained by reaction of KOH on aldehydes 6 or 4.

Full text of DOI:10.1016/0040-4039(91)80692-Y

Products guided by the article

Product name:(E)-2-(4-Chloro-phenyl)-3-ethylsulfanyl-4,4,4-trifluoro-but-2-enal

Cas No:136000-15-2

R&D Labs maybe for 136000-15-2

LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)
BioBioPha Co., Ltd

Contact:+86-871-65217109

Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences
Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA

Relevant to this article

Highly diastereoselective synthesis of tetrahydropyridines by a C-H activation-cyclization-reduction cascade

Doi:10.1021/ja2119833
(2012)
A novel synthesis of 1-aminoalkylphosphonates

Doi:10.1080/00397919108019793
(1991)
Regiospesific Synthesis of Polysubstituted Phenols via the Palladium-Catalyzed Enyne-Diyne [4 + 2] Cross-Benzannulation Pathway

Doi:10.1021/jo971817m
(1998)
2-Styrylchromone derivatives as potent and selective monoamine oxidase B inhibitors

Doi:10.1016/j.bioorg.2019.103285
(2019)
Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines

Doi:10.1002/chem.201100844
(2011)
First synthesis of [6-15N]-cladribine using ribonucleoside as a starting material

Doi:10.3987/COM-11-12382
(2012)

Article Doi