Gallium-mediated highly regioselective reaction of allyl-type bromide and propargyl-type bromide with aldehyde

Article abstract of DOI:10.1080/00397919908086104

In the presence of potassium iodide and lithium chloride, the one-pot reaction of gallium powder, allyl-type bromide and aldehyde shows very high selectivity favoring α-adducts. Under the same condition, the reaction of propargylic bromide with aldehyde e

Full text of DOI:10.1080/00397919908086104

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Gallium-Mediated Highly
Regioselective Reaction
of Allyl-Type Bromide and
Propargyl-Type Bromide With
Aldehyde
Ying Han a , Zhengfa Chi b & Yao-Zeng Huang a
a Shanghai Institute of Organic Chemistry, Chinese
Academy of Sciences , 354 Fenglin Lu, Shanghai,
200032, China
b Department of Chemistry , Chengdu Teachers'
College , Chengdu, 611930, China
Published online: 17 Sep 2007.
To cite this article: Ying Han , Zhengfa Chi & Yao-Zeng Huang (1999) Gallium-
Mediated Highly Regioselective Reaction of Allyl-Type Bromide and Propargyl-
Type Bromide With Aldehyde, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 29:8, 1287-1296, DOI:
10.1080/00397919908086104
To link to this article: http://dx.doi.org/10.1080/00397919908086104
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