Studies on taxane synthesis. III. Stereocontrolled synthesis of a twelve-membered lactam sulfide as a precursor of 4,8,11,11-tetramethyl-3-oxobicyclo[5.3.1]undec-8-ene

DOI: 10.1248/cpb.39.1359

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1359 - 1364 (1991)

Update date:2022-08-03

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Authors:

Ohtsuka Ohtsuka

Oishi Oishi

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Article abstract of DOI:10.1248/cpb.39.1359

Stereocontrolled synthesis of two twelve-membered lactam sulfides 37 and 38 as precursors of 8,11,11-trimethyl-3-oxobicyclo[5.3.1]undec-8-enes constituting the A and B rings of taxane-diterpenes was achieved. The key step involves a Diels-Alder reaction o

Full text of DOI:10.1248/cpb.39.1359

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