On the Stereoselective Opening of Chiral Dioxane Acetals. Nucleophile Dependence

DOI: 10.1021/jo00023a002

Source and publish data:

Journal of Organic Chemistry p. 6485 - 6487 (1991)

Update date:2022-08-04

Topics:

Authors:

Denmark, Scott E.

Almstead, Neil G.

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Article abstract of DOI:10.1021/jo00023a002

The stereoselective allylation of the chiral dioxane acetals 1 was found to be highly dependent on the nature of allylmetal reagent in the following order: Ph3Si (19/1) < Me3Si (58/1) < Ph3Sn (90/1) < Me3Ge (100/1) < n-Bu3Sn (>300/1).The allylation with a

Full text of DOI:10.1021/jo00023a002

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