Enantioselective Michael Reactions. Diastereoselective Reactions of Chlorotitanium Enolates of Chiral N-Acyloxazolidinones with Representative Electrophilic Olefins

DOI: 10.1021/jo00020a007

Source and publish data:

Journal of Organic Chemistry p. 5750 - 5752 (1991)

Update date:2022-09-26

Topics:

Authors:

Evans, David A.

Bilodeau, Mark T.

Somers, Todd C.

Clardy, Jon

Cherry, David

Kato, Yoko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00020a007

In the present study we wish to report the details of the diastereoselective reactions of titanium enolates derived from N-propionyloxazolidone 1 in inter- and intramolecular Michael reactions with ethyl vinyl ketone, methyl acrylate, and acrylonitrile (e

Full text of DOI:10.1021/jo00020a007

Products guided by the article

Product name:(S)-4-((S)-4-Benzyl-2-oxo-oxazolidine-3-carbonyl)-5-methyl-hexanenitrile

Cas No:136546-81-1

R&D Labs maybe for 136546-81-1

Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Shanghai Dynamic Industrial Co.,Ltd.

website:http://www.shdynamic.com

Contact:86-021 3392 6680

Address:Room 805 Information Tower, No.1403 Minsheng Road, Pudong New Area, Shanghai 200135, P. R. China
Fujian Wanke Pharmaceutical Co., LTD.

Contact:+86-598-5026002

Address:Economic development zone,jiangle county
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China

Relevant to this article

Highly efficient asymmetric Michael addition of aldehyde to nitroolefin using perhydroindolic acid as a chiral organocatalyst

Doi:10.1039/c2ob00003b
(2012)
Reactions of N-aryl(methyl, trifluoromethyl)sulfonyl-1,4-benzoquinone monoimines with sodium sulfi nates

Doi:10.1134/S107042801202011X
(2012)
Enantioselective activation of ethers by chiral organoaluminum reagents: Application to asymmetric Claisen rearrangement

Doi:10.1016/S0957-4166(00)86119-4
(1991)
Synthesis, characterization and crystal structure of N,N0-di[(E)-1-(2- hydoxyphenyl)methylidene]-2,6-naphthalenedicarbohydrazide

Doi:10.1007/s10870-011-0238-9
(2012)
An efficient synthesis of novel 2,4-disubstituted tetrahydroquinolines and quinolines

Doi:10.1016/j.tetlet.2012.02.043
(2012)
Simplified heterocyclic analogues of fluoxetine inhibit inducible nitric oxide production in lipopolysaccharide-induced BV2 cells

Doi:10.1248/bpb.34.538
(2011)

Article Doi