Enantioselective Michael Reactions. Diastereoselective Reactions of Chlorotitanium Enolates of Chiral N-Acyloxazolidinones with Representative Electrophilic Olefins

DOI: 10.1021/jo00020a007

Source and publish data:

Journal of Organic Chemistry p. 5750 - 5752 (1991)

Update date:2022-09-26

Topics:

Authors:

Evans, David A.

Bilodeau, Mark T.

Somers, Todd C.

Clardy, Jon

Cherry, David

Kato, Yoko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00020a007

In the present study we wish to report the details of the diastereoselective reactions of titanium enolates derived from N-propionyloxazolidone 1 in inter- and intramolecular Michael reactions with ethyl vinyl ketone, methyl acrylate, and acrylonitrile (e

Full text of DOI:10.1021/jo00020a007

Products guided by the article

Product name:(S)-4-((S)-4-Benzyl-2-oxo-oxazolidine-3-carbonyl)-5-methyl-hexanenitrile

Cas No:136546-81-1

R&D Labs maybe for 136546-81-1

chan jeans

Contact:15852689591

Address:jiangsu
SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city
Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands

Relevant to this article

Highly efficient asymmetric Michael addition of aldehyde to nitroolefin using perhydroindolic acid as a chiral organocatalyst

Doi:10.1039/c2ob00003b
(2012)
Reactions of N-aryl(methyl, trifluoromethyl)sulfonyl-1,4-benzoquinone monoimines with sodium sulfi nates

Doi:10.1134/S107042801202011X
(2012)
Enantioselective activation of ethers by chiral organoaluminum reagents: Application to asymmetric Claisen rearrangement

Doi:10.1016/S0957-4166(00)86119-4
(1991)
Synthesis, characterization and crystal structure of N,N0-di[(E)-1-(2- hydoxyphenyl)methylidene]-2,6-naphthalenedicarbohydrazide

Doi:10.1007/s10870-011-0238-9
(2012)
An efficient synthesis of novel 2,4-disubstituted tetrahydroquinolines and quinolines

Doi:10.1016/j.tetlet.2012.02.043
(2012)
Simplified heterocyclic analogues of fluoxetine inhibit inducible nitric oxide production in lipopolysaccharide-induced BV2 cells

Doi:10.1248/bpb.34.538
(2011)

Article Doi