Research on Chemical Intermediates p. 2513 - 2526 (2013)
Update date:2022-08-05
Topics: Mass spectrometry X-ray diffraction Purification Thermal Analysis Spectroscopic Analysis Selection of Natural Molecules Functionalization of Natural Molecules Synthesis of 2(5H)-Furanone Moiety Biphenyl Formation Optical Characterization Rheological Studies Electro-optical Measurements
Luo, Shi-He
Wang, Qun-Fang
Wang, Zhao-Yang
Peng, Pai
Using 4′-hexyloxybiphenyl-4-ol and N-(5-alkoxy-3-bromo-2(5H)- furanonyl) amino acids as reactants, a series of novel biphenyl liquid crystal compounds containing natural molecule moieties, such as menthol, borneol, and amino acids, were synthesized via esterification. The structures of all novel compounds were confirmed by FTIR, 1H NMR, 13C NMR, MS, and elemental analysis, and the liquid crystal properties of target compounds were characterized with DSC, XRD, and POM. The introduction of hexyloxy made the biphenyl esters have a potential to appear in mesomorphic phase and have a higher Tm, and bornyl moiety was more beneficial for the liquid crystal performance than a menthyl unit. Most compounds were mesomorphic phase liquid crystal molecules, and POM and XRD showed that they existed in smectic phase. These researches provide a theoretical basis for the synthesis of biphenyl ester liquid crystal materials via the utilization of 2(5H)-furanone derivates and natural molecules.
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