Cycloaddition of chlorosulfonyl isocyanate to 2H-azirines: Formation of [2+2+2] cycloadducts

Article abstract of DOI:10.1080/00397919108021065

Chlorosulfonyl isocyanate (CSI) reacts with 2H-azirines 1a-c at -78°C to form [2+2+2] cycloadducts 3a-c and 4a-c. The tricyclic aziridine derivatives 4a-c undergo CSI extrusion reactions and subsequent oxidation to the corresponding pyrazines 5a-c. Structural identifications of 3a-c and 4a-c are based on ir, nmr and mass spectral data.

Full text of DOI:10.1080/00397919108021065

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Cycloaddition of Chlorosulfonyl
Isocyanate to 2H-Azirines:
Formation of [2+2+2]
Cycloadducts
Joseph Daniel a & D. N. Dhar a
a Department of Chemistry , Indian Institute of
Technology , Kanpur, India , 208 016
Published online: 23 Sep 2006.
To cite this article: Joseph Daniel & D. N. Dhar (1991) Cycloaddition of Chlorosulfonyl
Isocyanate to 2H-Azirines: Formation of [2+2+2] Cycloadducts, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 21:15-16, 1649-1655, DOI: 10.1080/00397919108021065
To link to this article: http://dx.doi.org/10.1080/00397919108021065
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