
Journal of the Chemical Society. Perkin transactions I p. 2827 - 2832 (1996)
Update date:2022-08-03
Topics:
Bedford, Simon B.
Begley, Michael J.
Cornwall, Philip
Foreman, Joel P.
Knight, David W.
The Ito-Saegusa method has been used to generate benzofuran-2,3-quinodimethane 10 from the corresponding silyl acetate 17b in solution at -4°C. The intermediate reacts efficiently with a range of reactive Diels-Alder dienophiles with moderate to good levels of regioselection; the structure of the major diastereoisomer has been determined by X-ray analysis.
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