Dehydroxy substitution reactions of the anomeric hydroxy groups in some protected sugars initiated by anodic oxidation of triphenylphosphine

DOI: 10.1248/cpb.46.939

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 939 - 943 (1998)

Update date:2022-08-02

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Authors:

Maeda, Hatsuo

Matsumoto, Sayaka

Koide, Takashi

Ohmori, Hidenobu

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Article abstract of DOI:10.1248/cpb.46.939

The anodic transformation of 2,3:5,6-di-O-isopropylidene-α-D- mannofuranose (4) and 2,3,4,6-tetra-O-benzyl-D-glucopyranose (5) to the corresponding alkoxy phosphonium ions induces dehydroxy substitution of the sugars at the anomeric positions. Their dehyd

Full text of DOI:10.1248/cpb.46.939

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