Synthesis of 5-Deoxy-5-phenylphosphino- and 5-Phenylphosphinyl-D-glucopyranoses

DOI: 10.1246/bcsj.64.2398

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2398 - 2401 (1991)

Update date:2022-07-29

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Authors:

Hanaya, Tadashi

Akamatsu, Akihito

Kawamoto, Heizan

Armour, Margaret-Ann

Hogg, Alan M.

Yamamoto, Hiroshi

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Article abstract of DOI:10.1246/bcsj.64.2398

(5R and 5S)-3-O-Acetyl-5-deoxy-1,2-O-isopropylidene-5-<(methoxy)phenylphosphinyl>-6-O-(tetrahydro-2-pyranyl)-α-D-xylo-hexofuranoses (7) were prepared from 3-O-acetyl-5,6-dideoxy-6-nitro-α-D-xylo-hex-5-enofuranose in 4 steps.Reduction of 7 with sodium dihy

Full text of DOI:10.1246/bcsj.64.2398

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