Synthesis of the Functionalized Cyclohexanecarbaldehyde Derivative. A Potential Key Compound for Total Synthesis of Optically Active Tetrodotoxin

DOI: 10.1246/cl.1991.1559

Source and publish data:

Chemistry Letters p. 1559 - 1562 (1991)

Update date:2022-07-30

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Authors:

Sato, Ken-ichi

Kajihara, Yasuhiro

Nakamura, Yutaka

Yoshimura, Juji

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Article abstract of DOI:10.1246/cl.1991.1559

Oxidation of 1_L-(1,2,3',4,5/3,6)-3-hydroxymethyl-2,4,5-tri-O-methoxymethyl-3,3'-O-methylene-6-nitro-2,3,4,5-tetrahydroxycyclohexanecarbaldehyde dimethyl acetal with potassium t-butoxide and m-chloroperbenzoic acid has given corresponding carbon

Full text of DOI:10.1246/cl.1991.1559

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