Synthesis of the Functionalized Cyclohexanecarbaldehyde Derivative. A Potential Key Compound for Total Synthesis of Optically Active Tetrodotoxin

Article abstract of DOI:10.1246/cl.1991.1559

Oxidation of 1_L-(1,2,3',4,5/3,6)-3-hydroxymethyl-2,4,5-tri-O-methoxymethyl-3,3'-O-methylene-6-nitro-2,3,4,5-tetrahydroxycyclohexanecarbaldehyde dimethyl acetal with potassium t-butoxide and m-chloroperbenzoic acid has given corresponding carbon