Simple Synthesis and the Diels-Alder Reaction of 3-(p-Tolylthio)-2-(trimethylsilyloxy)-1,3-butadiene

DOI: 10.1246/cl.1991.1577

Source and publish data:

Chemistry Letters p. 1577 - 1578 (1991)

Update date:2022-08-05

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Authors:

Kosugi, Hiroshi

Hoshino, Kunihide

Uda, Hisashi

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Article abstract of DOI:10.1246/cl.1991.1577

The reaction of 3-(p-tolylsulfinyl)-2-butanone with trimethylsilyl trifluoromethanesulfonate in the presence of diisopropylethylamine gave 3-(p-tolylthio)-2-(trimethylsilyloxy)-1,3-butadiene (2) quantitatively.The Diels-Alder reactions of 2 and the relate

Full text of DOI:10.1246/cl.1991.1577

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Product name:4-p-Tolylsulfanyl-3-trimethylsilanyloxy-cyclohex-3-enecarboxylic acid methyl ester

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