Samarium diiodide promoted spirolactonization of cycloalkanones

DOI: 10.1016/S0040-4020(01)96158-7

Source and publish data:

Tetrahedron p. 7037 - 7044 (1991)

Update date:2022-08-04

Topics:

Authors:

Csuk Csuk

Abdou Abdou

Kratky Kratky

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Article abstract of DOI:10.1016/S0040-4020(01)96158-7

Reaction of cycloalkanones with methyl 3-bromopropionate and SmI₂ afforded formation of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-1-oxaspiro[n,m]alkan-2-ones.

Full text of DOI:10.1016/S0040-4020(01)96158-7

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