Tetrahedron Letters p. 4943 - 4946 (1983)
Update date:2022-08-03
Topics:
Bunce, Richard A.
Schlecht, Matthew F.
Dauben, William G.
Heathcock, Clayton H.
O-Silylated ketene acetals have been added to activated enones possessing varying degrees of β-substitution under 15 kbar (1.5 GPa) presure in acetonitrile at 20 deg C to afford good to excellent yields of 1,4-adducts.The additions at elevated pressures a
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