Organic Reactions at High Pressure. Conjugate Additions of O-Silylated Ketene Acetals to Activated Enones

DOI: 10.1016/S0040-4039(01)99817-X

Source and publish data:

Tetrahedron Letters p. 4943 - 4946 (1983)

Update date:2022-08-03

Topics:

Authors:

Bunce, Richard A.

Schlecht, Matthew F.

Dauben, William G.

Heathcock, Clayton H.

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Article abstract of DOI:10.1016/S0040-4039(01)99817-X

O-Silylated ketene acetals have been added to activated enones possessing varying degrees of β-substitution under 15 kbar (1.5 GPa) presure in acetonitrile at 20 deg C to afford good to excellent yields of 1,4-adducts.The additions at elevated pressures a

Full text of DOI:10.1016/S0040-4039(01)99817-X

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