Journal of the American Chemical Society p. 2885 - 2888 (2016)
Update date:2022-08-03
Topics:
Wu, Qian
Luo, Yi
Lei, Aiwen
You, Jingsong
We have disclosed for the first time the copper-promoted C≡N triple bond cleavage of coordinated cyanide anion under a dioxygen atmosphere, which enables a nitrogen transfer to various aldehydes. Mechanistic study of this unprecedented transformation suggests that the single electron-transfer process could be involved in the overall course. This protocol provides a new cleavage pattern for the cyanide ion and would eventually lead to a more useful synthetic pathway to nitriles from aldehydes.
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