Tetrahedron Letters p. 4525 - 4528 (1991)
Update date:2022-08-04
Topics:
Chida, Noritaka
Ohtsuka, Masami
Ogawa, Seiichiro
The stereoselective total synthesis of the title compound starting from D-glucose is described.The key steps in this synthesis are Ferrier rearrangement to construct the optically active cyclohexenone (C-ring), and Pd-catalyzed intramolecular Heck reactio
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