Structural Analysis of cis-Bicyclic Ketones by X-ray Crystallography. Impact of the Observed Conformational Crossover on ?-Facially Diastereoselective Nucleophilic Additions to This Class of Ketones and on the Stereochemical Course of Electrophilic

DOI: 10.1021/jo00027a018

Source and publish data:

Journal of Organic Chemistry p. 86 - 96 (1992)

Update date:2022-08-05

Topics:

Authors:

Paquette, Leo A.

Underiner, Ted L.

Gallucci, Judith C.

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Article abstract of DOI:10.1021/jo00027a018

X-ray crystallographic studies clearly show that cis-bicyclic ketones 1 having n equal to 7 or less are conformationally predisposed such that the rigid chair cyclohexanone ring projects the polymethylene chaine diaxially.In contrast, an increase i

Full text of DOI:10.1021/jo00027a018

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