Tetrahedron Letters p. 4189 - 4192 (1993)
Update date:2022-08-03
Topics:
Genet, Jean Pierre
Blart, Errol
Savignac, Monique
Lemeune, Stephane
Paris, Jean-Marc
The Allyloxycarbonyl (Alloc) moiety can be removed smoothly and selectively in good yield (70-99%) from allylic esters, carbamates and carbonates by aqueous Pd (0) catalyzed allyl transfer to diethylamine as the accepting nucleophile. The method has been successfully used for deprotection of a wide range of secondary amines.
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