Chelation Control in the Aldol Reaction of Tetronic Acid. Application to the Synthesis of Pentoses, Arabitol and Ribitol

DOI: 10.1246/cl.1991.1861

Source and publish data:

Chemistry Letters p. 1861 - 1864 (1991)

Update date:2022-08-04

Topics:

Authors:

Honda, Toshio

Hayakawa, Tomohisa

Kondoh, Hirotsune

Okuyama, Akihiko

Tsubuki, Masayoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1991.1861

The aldol reaction of lithium enolates of tetronates with (R)-2,3-O-cyclohexylideneglyceraldehyde afforded the chelation controlled products stereoselectively.The conversion of the aldol products into arabitol and ribitol was also described.

Full text of DOI:10.1246/cl.1991.1861

Products guided by the article

Product name:(S)-4-Benzyloxy-5-((R)-(R)-1,4-dioxa-spiro[4.5]dec-2-yl-triethylsilanyloxy-methyl)-5H-furan-2-one

Cas No:137734-20-4

R&D Labs maybe for 137734-20-4

WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
WUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.

Contact:13861062998

Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
KAIYUAN CHEMICAL COMPANY LIMITED.

website:http://www.kaiyuanchem.com

Contact:+86-22-59891255/66/77

Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.

Relevant to this article

Organocatalytic one-pot asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones

Doi:10.1039/c6ra01247g
(2016)
Catalyst-free, visible light irradiation promoted synthesis of spiroacenaphthylenes and 1H-pyrazolo[1,2-b]phthalazine-5,10-diones in aqueous ethyl lactate

Doi:10.1016/j.jphotochem.2020.113041
(2021)
Absolute configuration of lactams and oxazolidinones using kinetic resolution catalysts

Doi:10.1021/ol303239t
(2013)
Synthesis of β-Cyano Ketones Promoted by a Heterogeneous Fluoride Catalyst

Doi:10.1002/adsc.201600287
(2016)
Fragmentation of carbohydrate anomeric alkoxyl radicals: Synthesis of chiral polyhydroxylated β-iodo- and alkenylorganophosphorus(V) compounds

Doi:10.1002/ejoc.201402387
(2014)
Aeruginazole A, a novel thiazole-containing cyclopeptide from the cyanobacterium microcystis sp.

Doi:10.1021/ol1014015
(2010)

Article Doi