Chelation Control in the Aldol Reaction of Tetronic Acid. Application to the Synthesis of Pentoses, Arabitol and Ribitol

DOI: 10.1246/cl.1991.1861

Source and publish data:

Chemistry Letters p. 1861 - 1864 (1991)

Update date:2022-08-04

Topics:

Authors:

Honda, Toshio

Hayakawa, Tomohisa

Kondoh, Hirotsune

Okuyama, Akihiko

Tsubuki, Masayoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1991.1861

The aldol reaction of lithium enolates of tetronates with (R)-2,3-O-cyclohexylideneglyceraldehyde afforded the chelation controlled products stereoselectively.The conversion of the aldol products into arabitol and ribitol was also described.

Full text of DOI:10.1246/cl.1991.1861

Products guided by the article

Product name:(S)-4-Benzyloxy-5-((R)-(R)-1,4-dioxa-spiro[4.5]dec-2-yl-triethylsilanyloxy-methyl)-5H-furan-2-one

Cas No:137734-20-4

R&D Labs maybe for 137734-20-4

SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY

Contact:0086-0757-85609331

Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
Shanghai Demand Chemical Co., ltd，China

Contact:86-021-55237578/55239122

Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
Shaanxi Sinuote Biotech Co.,Ltd

Contact:+86-29-68859685

Address:No 18,Taiyuan Road ,Xi'an city ,China

Relevant to this article

Organocatalytic one-pot asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones

Doi:10.1039/c6ra01247g
(2016)
Catalyst-free, visible light irradiation promoted synthesis of spiroacenaphthylenes and 1H-pyrazolo[1,2-b]phthalazine-5,10-diones in aqueous ethyl lactate

Doi:10.1016/j.jphotochem.2020.113041
(2021)
Absolute configuration of lactams and oxazolidinones using kinetic resolution catalysts

Doi:10.1021/ol303239t
(2013)
Synthesis of β-Cyano Ketones Promoted by a Heterogeneous Fluoride Catalyst

Doi:10.1002/adsc.201600287
(2016)
Fragmentation of carbohydrate anomeric alkoxyl radicals: Synthesis of chiral polyhydroxylated β-iodo- and alkenylorganophosphorus(V) compounds

Doi:10.1002/ejoc.201402387
(2014)
Aeruginazole A, a novel thiazole-containing cyclopeptide from the cyanobacterium microcystis sp.

Doi:10.1021/ol1014015
(2010)

Article Doi