Chelation Control in the Aldol Reaction of Tetronic Acid. Application to the Synthesis of Pentoses, Arabitol and Ribitol

DOI: 10.1246/cl.1991.1861

Source and publish data:

Chemistry Letters p. 1861 - 1864 (1991)

Update date:2022-08-04

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Authors:

Honda, Toshio

Hayakawa, Tomohisa

Kondoh, Hirotsune

Okuyama, Akihiko

Tsubuki, Masayoshi

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Article abstract of DOI:10.1246/cl.1991.1861

The aldol reaction of lithium enolates of tetronates with (R)-2,3-O-cyclohexylideneglyceraldehyde afforded the chelation controlled products stereoselectively.The conversion of the aldol products into arabitol and ribitol was also described.

Full text of DOI:10.1246/cl.1991.1861

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