Direct synthesis of methyl 2-diazo-4-aryl-3-butenoates and their application to the enantioselective synthesis of 4-aryl-4-(1-naphthyl)-2-butenoates

DOI: 10.1016/j.tetasy.2006.01.023

Source and publish data:

Tetrahedron Asymmetry p. 665 - 673 (2006)

Update date:2022-07-29

Topics:

Authors:

Davies, Huw M.L.

Yang, Jaemoon

Manning, James R.

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Article abstract of DOI:10.1016/j.tetasy.2006.01.023

An improved one-flask synthesis of various methyl 2-diazo-4-aryl and 4-heteroaryl-3-butenoates, precursors to donor/acceptor substituted carbenoids, is described. Their Rh₂(S-DOSP)₄ catalyzed reaction with 1-acetoxy-3,4-dihydronaphth

Full text of DOI:10.1016/j.tetasy.2006.01.023

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Product name:3-Butenoic acid, 4-(3,4-dimethoxyphenyl)-, methyl ester

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