Unexpected MIMIRC Annulation Between a Lithium Dienolate and Methyl Acrylate

DOI: 10.1016/0040-4039(91)80076-I

Source and publish data:

Tetrahedron Letters p. 5531 - 5534 (1991)

Update date:2022-07-29

Topics:

Authors:

Jaafar, Akram

Alilou, El Houssine

Reglier, Marius

Waegell, Bernard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80076-I

We describe an unusual <2+2+2> MIMIRC reaction between a lithium dienolate 6 and methyl acrylate.The more classical double Michael addition cyclisation provides an efficient entry towards key intermediate 5 for 2-isocyanopupukeanane 1 synthesis.

Full text of DOI:10.1016/0040-4039(91)80076-I

Products guided by the article

Product name:(1S,6S,8R,11S)-2,6-Dimethyl-9-oxo-10-oxa-tricyclo[6.2.2.0^1,6]dodec-2-ene-11-carboxylic acid methyl ester

Cas No:137762-21-1

R&D Labs maybe for 137762-21-1

Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road

Relevant to this article

Vascular barrier protective effects of eckol and its derivatives

Doi:10.1016/j.bmcl.2012.04.026
(2012)
Highly efficient one-pot, three-component synthesis of β-aminoketones catalyzed by Fe(O₂CCF₃)₃

Doi:10.1080/00397911.2011.569866
(2012)
Ionic liquid-mediated facile synthesis and antimicrobial study of thiazolo [2,3-b]benzo[h]quinazolines and thiazino[2,3-b] benzo-[h]quinazolines

Doi:10.1080/10426507.2011.647145
(2012)
A general method for detecting protease activity via gelation and its application to artificial clotting

Doi:10.1039/c2cc31537h
(2012)
Gold-catalysed oxyarylation of styrenes and mono- and gem-disubstituted olefins facilitated by an iodine(III) oxidant

Doi:10.1002/chem.201103061
(2012)
Lanthanide complexes combined with chiral salen ligands: Application in the enantioselective epoxidation reaction of α,β-unsaturated ketones

Doi:10.1039/c9ra01529a
(2019)

Article Doi