Tetrahedron Letters p. 1007 - 1010 (1996)
Update date:2022-08-03
Topics:
Montes, Imber Flores
Burger, Ulrich
Cross-over experiments unveil that the mechanism of the title reaction consists in cleavage of enol esters by cyanide with transient formation of acyl cyanides. These react as 'soft' C-acylating agents with the enolates freed in the initial step. Use is made of the acyl cyanide derived from pyrrole-2-carboxylic acid to set up the triketide type skeleton 12 of the antibiotic pyoluteorin 16. The aromatization of 12 with mercuric acetate gave the pyrrolo[a]indolone 18.
View MoreContact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Chengdu Green Young Biopharmaceutical INC
Contact:+86-28-85337952
Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000
Sichuan Sangao Biochemical Co., Ltd
Contact:+86-28-84874233
Address:19F, Bldg.2, Shudu Center, Tianfu 2nd St., Hi-tech zone, Chengdu 610041, Sichuan Province, China.
shanghai jiuling chemical co.,ltd.
Contact:+86-21-50387295
Address:Zaozhuang Road, Pudong, Shanghai City. China
Nanjing Spring & Autumn Biological Engineering Co., Ltd.
Contact:86-180510-83338
Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China
Doi:10.1016/S0040-4020(01)81955-4
(1991)Doi:10.1016/S0040-4039(00)79430-5
(1991)Doi:10.1016/j.ijms.2010.10.006
(2011)Doi:10.1002/chem.201101918
(2012)Doi:10.1021/ml300106p
(2012)Doi:10.1021/acs.organomet.6b00814
(2017)
