Photophysics and Photochemistry of Nitroanthracenes Part 1. - Primary Processes in the Photochemical Reactions of 9-Benzoyl-10-nitroanthracene and 9-Cyano-10-nitroanthracene studied by Steady-state Photolysis and Nanosecond Laser Photolysis

DOI: 10.1039/ft9918703365

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 3365 - 3372 (1991)

Update date:2022-08-03

Topics:

Authors:

Hamanoue, Kumao

Nakayama, Toshihiro

Ushida, Kiminori

Kajiwara, Kanji

Yamanaka, Shigenobu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/ft9918703365

The genuine phosphorescence spectra of the title compounds (XNA) have been clearly observed at 77 K in EPA (diethyl ether-isopentane-ethanol 5:5:2 volume ratio).Also, the time-resolved absorption spectra obtained at the end of nanosecond laser pulse at 77 K (in EPA) and at room temperature (in ethanol and benzene) have been ascribed to the superposition of the absorptions of the lowest triplet XNA <³XNA(T₁)> on those of the corresponding anthryloxy radicals (XAO.).The decay of ³XNA(T₁) is not accompanied by the formation of XAO. and the following results are obtained. (1) In ethanol at room temperature, the first-order decay of XAO. corresponds to hydrogen-atom abstraction by XAO. from the solvent, giving rise to the formation of corresponding anthrols (XAOH), while the second-order reaction of XAO. with nitrogen(II) oxide (NO.) yields the corresponding nitrosoanthrones (XNSAN) which decompose very slowly into XAO. and NO. followed by the rapid formation of XAOH. (2) In benzene at room temperature no formation of XAOH is observed, but there exists an equilibrium between XAO.(+NO.) and XNSAN.All these results support our previous conclusion that the nitro -> nitrite rearrangement of XNA does not occur for the lowest triplet states of ??* character but does occur for the higher triplet states of n?* character, followed by the cleavage of the nitrites to XAO. and NO..

Full text of DOI:10.1039/ft9918703365

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:9(10H)-Anthracenone, 10-benzoyl-10-nitroso-

Cas No:137888-23-4

R&D Labs maybe for 137888-23-4

Engineering Research Center of Pesticide, Heilongjiang Province

Contact:+86-451-86609001

Address:No.74 of Xuefu Road, Nangang District,
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China
A-Chem Technologies Co.,Ltd.

Contact:+86-512-69561895

Address:No.111, Building A4, 218 Xinghu Street, Suzhou Industrial Park, P. R. China
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou

Relevant to this article

Synthesis and antimitotic activity of alkoxy-substituted 1-aryl-3-(arylamino)alkenones

Doi:10.1007/s11172-015-0883-9
(2015)
Total synthesis of Akuammiline alkaloid (-)-vincorine via intramolecular oxidative coupling

Doi:10.1021/ja303602f
(2012)
Photochemistry of azoalkane: Formation of the rearrangement product by photoinduced electron transfer of the pyrazoline derivative

Doi:10.1039/c39910001451
(1991)
Generation of 1-aryl-3-methoxycarbonylnitrilimines and their reactions with unsaturated hydrocarbons

Doi:10.1007/s11172-011-0251-3
(2011)
Synthesis of fused thiazolo[3,2-a]pyrimidinones: N-aryl-2-chloroacetamides as doubly electrophilic building blocks

Doi:10.1016/j.tetlet.2013.11.001
(2014)
A rigid disulfide-linked nitroxide side chain simplifies the quantitative analysis of PRE data

Doi:10.1007/s10858-011-9545-x
(2011)

Article Doi