Journal of the Chemical Society. Chemical communications p. 263 - 266 (1995)
Update date:2022-07-29
Topics:
Magnus, Philip
Roe, Michael B.
Hulme, Christopher
Treatment of triisopropylsilyl enol ethers with PhIO/TMSN3/TEMPO(cat.) -45 deg C results in 1,2-bis-azidonation, which appears to occur through a radical addition process; the 1-azido group can be replaced by carbon nucleophiles such as allyl,
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