Reductive Beckmann fragmentation of α-alkoxycycloalkanone oxime acetates

DOI: 10.1016/S0040-4039(00)92387-6

Source and publish data:

Tetrahedron Letters p. 5367 - 5368 (1991)

Update date:2022-08-05

Topics:

Authors:

Fujioka, Hiromichi

Yamamoto, Hideaki

Miyazaki, Makoto

Yamanaka, Takeshi

Takuma, Kazuhiro

Kita, Yasuyuki

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Article abstract of DOI:10.1016/S0040-4039(00)92387-6

The title reaction was achieved with Et₃SiH in the presence of a catalytic amount of CF₃SO₃SiMe₃. The reaction was applied to the synthesis of (±)-exo-brevicomine.

Full text of DOI:10.1016/S0040-4039(00)92387-6

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